Enhancement

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Definition

Enhancement, when used in gemological conversation, stands for a man-induced treatment which improves the appearance or durability of a gemstone.

Introduction

Gem minerals are rare, durable and beautiful by definition; this is what distinguishes them from all other minerals. Most gem deposits do not solely yield gem grade stones though. In fact, every gem miner will be able to tell you that only a small percentage of the stones he unearths is fit for jewelry. There may be too much or too little color in the stone, the color may be of an undesirable hue or it may be fractured or unstable. Since the demand for gemstones always outweighs the supply, causing their high prices, this is where these non gem grade stones become economically interesting. If a miner can offload his lower grade stones as well as his prime stones his business has got a much better chance on surviving.

Because the natural, untreated product is extremely rare, high prices are commanded throughout the line of production from mine to consumer. Non gem grade stones that are fit for treatment are in greater supply and don't enjoy this natural rarity to the same extend. They can be bought cheap from miners keen to cash their low quality stones so consequently should command lower prices. Relatively inexpensive treatments are then performed to make the stones look exactly like the popular natural product. All too often it takes an expert to distinguish between the natural and treated stones. Now here's where problems may arise. This resemblance makes it possible for unscrupulous dealers to sell the treated product as natural and command top dollar. The proper way to deal with these stones is to disclose the treatments properly.

The price difference between natural and treated goods isn't solely a rarity factor. In some cases the enhanced stones resemble the natural product in appearance but not in durability. A glass-filled ruby for instance isn't as resistant to abrasion and chemical attack as the real deal. This is another reason proper disclosure is of the utmost importance, things that wouldn't affect a natural stone may ruin a treated one.

So, are treatments an evil thing? The answer is no, not when they are properly represented as being treated in one or the other way. The increased prosperity that occurred over the last century allows far more people to indulge in wearing gemstones. Where gems were reserved for the nobility and wealthy in the past, now billions of people have surplus income and are happy to show that off by wearing expensive personal decoration. The demand for gemstones is so big these days that without gem treatments the prices for natural goods would go through the roof.

Treated goods have become an essential part of the jewelry trade. Consumers need them in order to meet their increased demand and the miner needs them to make a consistant living. Without the selling of treatable stones he would be left at the mercy of his luck of finding a gem grade stone every day. It is estimated that 80% of the worlds gemstones are mined by independent artisanal miners[1]and it is important that this group can make a decent living. Without these hard working souls these beautiful gifts of nature wouldn't reach you.

And for the jewelry historian? To those investigating the age of a jewelry item treatments may provide very helpful clues. We have a reasonable good idea of the invention dates of the different treatments and finding a stone which is clearly treated in a way that was invented in the 1970's in a Victorian jewel should raise alarm bells. The stone may either be a replacement of an old stone or indicate a recent reproduction. Either way a closer look is at place in such cases and spotting a modern treatment may contribute to the correct identification of a well made reproduction as such.

Treatments

Below you will find all possible treatments, the gemstones which can be enhanced by these treatments together with the effect of the treatment and the supposed introduction dates of these techniques. Follow the links below to learn more about specific treatments.

Material Effect Date of introduction
Amber Small fractures; sun spangles

Clarity enhancement Aged look; darkening of surface

BC Wieslaw Giertowski
Beryl Eliminating the yellow color component in aquamarine ?
Corundum Enhance clarity by dissolving silk into the corundum lattice


Enhance/change color.

Introducing asterism by exsolving of silk

BC


1960’s: Gueda sapphire to blue (Crowningshield 1966, 1970, Beesley, 1982.)
1949, Burdick and Glenn patent

Diamond Annealing after irradiation to introduce color

1957 Crowningshield, G&G Winter 1957

Jade Lightening or darkening of color


Introducing aged look

?


?

Quartz Changing color BC
Tanzanite Changing of brown into blue 1967?
Topaz Changing of color, Annealing after irradiation 1957 stable blue color product of irradiation in combination with annealing. Pough, 1957
Tourmaline Changing color ?
Zircon Changing color

Recrystallization of metamict stones

BC ?
Corundum Surface diffusion, changing color


Bulk diffusion, changing color

late 1970s Crowningshield, 1979


Late 1990’s - 2000 Emmett et al

Feldspar Pipe diffusion, changing color 2008, (Milisenda, 2008, Emmett, 2009)
Beryl Changing color 1947 (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
Corundum Changing color 1947 (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
Diamond Changing color

1914, Irradiated diamonds by immersion in radium bromide, (Pough & Schulke as reported in G&G spring 1951)
1938, Cyclotron irradiated diamonds (Hardy G&G summer 1949)

Pearl Darkening 1967, (R.T. Liddicoat G&G spring 1967)
Quartz Changing/introducing color 1949 (G&G winter 1949)
Spodumene Changing color 1947 (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
Scapolite Changing/introducing color (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
Topaz Changing color 1909 irradiation of pink topaz to orange (Pough & Rogers, 1947)


1957 stable blue color product of irradiation in combination with annealing, (Pough, 1957)

Tourmaline Changing color (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
Zircon changing color (structure from crystalline to metamict) (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
Beryl (Emerald) Clarity/color enhancement by (colored) oil or epoxy resin Oil – BC


Epoxy resin – 1994 ( Levy, 1994 ICA gazette, april)

Corundum Clarity/color enhancement


Oiling

Glass filling





Flux healing




BC


BC

Glass filling of surface reaching cavities in rubies 1984 (http://www.ruby-sapphire.com/foreign-affairs.htm Hughes, 1992]

Flux healing of surface reaching cavities in rubies 1992 (http://www.ruby-sapphire.com/foreign-affairs.htm Hughes, 1992)

Diamond Glass filling 1982, Zvi Yehuda
Jade color/stability enhancement:


Impregnation
B-jade
C-jade

?

? ?

Opal Impregnation:

stability enhancement

?
Turquoise Impregnation:

color and stability enhancement

?
All gemstones Adding a colored layer BC
All transparent gemstones Adding a transparent layer with different optical density than the gem to create color by interference effects Early 1940’s (Gubelin, G&G Winter 1949 p. 243)
Diamond Improving color grade of a diamond by application of coating techniques resulting from WOII research: Vaccuum sputtering of Fluorides on pavilion or girdle first lab alert 1952

Law enacted against undisclosed marketing of coated diamonds in 1962 by NY State.

All transparent gemstones Enhancing/introducing color, increasing brilliance Minoan times (Ball, 1950) Roman times (Pliny 76 AD)
All gem materials Introducing/enhancing color BC (Pliny 76 AD)
Diamond Color enhancement 1960'ies
Diamond Clarity enhancement 1970 (Crowningshield G&G fall 1970)

References

  1. G&G Fall 2010, 'An Era of Sweeping Change in Diamond and Colored Stone Production and Markets'. Shor, Russel & Weldon, Robert.
Lang Antiques
Lang Antiques