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Enhancement

Laser Drilled Diamond. The Visible Drill Channels are Not All Individual Channels, for the Most Part, They are Reflections.
Image Courtesy of Conny Forsberg, FGA.

Definition

Enhancement, when used in gemological conversation, stands for a man-induced treatment which improves the appearance or durability of a gemstone.

Introduction

Gem minerals are rare, durable and beautiful by definition; this is what distinguishes them from all other minerals. Most gem deposits do not solely yield gem grade stones though. In fact, every gem miner will be able to tell you that only a small percentage of the stones he unearths is fit for jewelry. There may be too much or too little color in the stone, the color may be of an undesirable hue or it may be fractured or unstable. Since the demand for gemstones always outweighs the supply, causing their high prices, this is where non- gem grade stones become economically interesting. If a miner can offload his lower grade stones as well as his prime stones his business has got a much better chance of surviving.

Because the natural, untreated product is extremely rare, high prices are commanded throughout the line of production from mine to consumer. Non-gem grade stones that are fit for treatment are in greater supply and don’t enjoy this natural rarity to the same extent. They can be bought cheaply from miners keen to cash in on their low-quality stones. Relatively inexpensive treatments are then performed to make the stones look exactly like the popular natural product. All too often it takes an expert to distinguish between the natural and treated stones. Now here’s where problems may arise. This resemblance makes it possible for unscrupulous dealers to sell the treated product as natural and command top dollar. The proper way to deal with these stones is to disclose the treatments in full.

In some cases, the enhanced stones resemble the natural product in appearance but not in durability. A glass-filled ruby, for instance, isn’t as resistant to abrasion and chemical attack as the real deal. This is another reason proper disclosure is of the utmost importance, things that wouldn’t affect a natural stone may ruin a treated one.

So, are treatments an evil thing? The answer is no, not as long as they are properly disclosed. The increased prosperity that occurred over the last century allows far more people to indulge in wearing gemstones. Where gems were once reserved for the nobility and the wealthy in the past, now billions of people have surplus income and are happy to show that off by wearing expensive personal decoration. The demand for gemstones is so large these days that without gem treatments the prices for natural goods would go through the roof.

Treated goods have become an essential part of the jewelry trade. Consumers need them in order to meet their increased demand and the miner needs them to make a consistent living. Without the selling of treatable stones, he would be left at the mercy of his luck of finding a gem grade stone every day. It is estimated that 80% of the world’s gemstones are mined by independent artisanal miners1 and it is important that this group can make a decent living. Without these hardworking souls, these beautiful gifts of nature wouldn’t reach you.

And for the jewelry historian? To those investigating the age of a jewelry item treatments may provide very helpful clues. We have a reasonably good idea of the invention dates of the different treatments and finding a stone which is clearly treated in a way that was invented in the 1970’s in a Victorian jewel should raise alarm bells. The stone may either be a replacement of an old stone or indicate a recent reproduction. Either way, a closer look is warranted in such cases and spotting a modern treatment may contribute to the correct identification of a well-made reproduction as such.

Treatments

Below you will find all possible treatments, the gemstones which can be enhanced by these treatments together with the effect of the treatment and the supposed introduction dates of these techniques. Follow the links below to learn more about specific treatments.
MaterialEffectDate of Introduction
TreatmentHeat Treatment
AmberSmall fractures; Sun Spangles
Clarity Enhancement Aged Look; Darkening of Surface.
BC
Wieslaw Giertowski
BerylEliminating the Yellow Color Component in Aquamarine.? BC
CorundumEnhance/Change Color.
Introducing Asterism by Exsolving of Silk.
Enhance Clarity by Dissolving Silk into the Corundum Lattice.
1960’s: Gueda sapphire to blue
(Crowningshield 1966, 1970, Beesley, 1982.)
1949, Burdick and Glenn Patent.
DiamondAnnealing After Irradiation to Introduce Color.1957 Crowningshield, G&G Winter 1957
JadeLightening or Darkening of Color.
Introducing Aged Look.
?
?
QuartzChanging Color. BC
TanzaniteChanging Brown into Blue.irradiation in combination with annealing. Pough, 1957
TopazChanging Color, Annealing After Irradiation.1957 stable blue color product of irradiation in combination with annealing. Pough, 1957
TourmalineChanging Color. ?
ZirconChanging Color. Recrystallization of Metamict Stones BC
?
TreatmentHeat + Additive a.k.a Diffusion
CorrundumSurface Diffusion, Changing Color.
Bulk Diffusion, Changing Color.
late 1970s Crowningshield, 1979
Late 1990’s - 2000 Emmett et al
FeldsparPipe Diffusion, Changing Color2008, (Milisenda, 2008, Emmett, 2009)
TreatmentIrradiation
BerylChanging Color.1947 (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
CorundumChanging Color.1947 (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
DiamondChanging Color.1914, Irradiated diamonds by immersion in radium bromide, (Pough & Schulke as reported in G&G spring 1951)
1938, Cyclotron irradiated diamonds (Hardy G&G summer 1949)
PearlDarkening.1967, (R.T. Liddicoat G&G spring 1967)
QuartzChanging/Introducing Color.1949 (G&G winter 1949)
SpodumeneChanging Color.1947 (American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
ScapoliteChanging/Introducing Color.(American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
TopazChanging Color.1909 irradiation of pink topaz to orange (Pough & Rogers, 1947) 1957 stable blue color product of irradiation in combination with annealing, (Pough, 1957)
TourmalineChanging Color.(American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
ZirconChanging Color. (Structure from Crystalline to Metamict)(American Mineralogist, vol. 32, p 31-43 jan-feb 1947. Reported in G&G spring 1947)
TreatmentFilling
Beryl (Emerald)Clarity/Color Enhancement by (Colored) Oil or Epoxy Resin.Oil – BC
Epoxy resin – 1994 ( Levy, 1994 ICA gazette, april)
CorundumClarity/Color Enhancement:

  • Oiling

  • Glass filling

  • Flux healing
  • BC
    Glass filling of surface reaching cavities in rubies 1984 (http://www.ruby-sapphire.com/foreign-affairs.htm Hughes, 1992]Flux healing of surface reaching cavities in rubies1992 (http://www.ruby-sapphire.com/foreign-affairs.htm Hughes, 1992)
    DiamondGlass Filling.1982, Zvi Yehuda
    JadeColorS/tability Enhancement:

  • Impregnation

  • B-jade

  • C-jade

  • ?
    ?
    ?
    OpalImpregnation: Stability Enhancement.?
    TourquoiseImpregnation: Stability and Color Enhancement.?
    TreatmentCoating
    All GemstonesAdding a Colored Layer.BC
    All Transparent GemstonesAdding a Transparent Layer with Different Optical Density Than the Gem to Create Color by Interference Effects.Early 1940’s (Gubelin, G&G Winter 1949 p. 243)
    DiamondImproving Color Grade of a Diamond by Application of Coating Techniques Resulting from WOII Research: Vacuum Sputtering of Fluorides on Pavilion or Girdle.First Lab Alert 1952 Law Enacted Against Undisclosed Marketing of Coated Diamonds in 1962 by NY State.
    TreatmentFoiling
    All Transparent GemstonesEnhancing/Introducing Color, Increasing Brilliance.Minoan Times (Ball, 1950) Roman Times (Pliny 76 AD).
    TreatmentDying
    All Gem MaterialsIntroducing/Enhancing Color.BC (Pliny 76 AD)
    TreatmentHPHT
    DiamondClarity Enhancement.1960s
    TreatmentLaser Drilling
    DiamondClarity Enhancement.1970 (Crowningshield G&G Fall 1970)

     

    Notes

    1. G&G Fall 2010, ‘An Era of Sweeping Change in Diamond and Colored Stone Production and Markets’. Shor, Russel & Weldon, Robert.